Four main types of faults can occur at the DC side of any Photovoltaic System (PVS). These faults are quite dangerous and can cause permanent damage to the photovoltaic modules if not addressed promptly. The faults include open circuit, short circuit, degradation, and partial shading. Short circuit faults are classified into line-to-line (L-L) and line-to-ground (L-G). Detecting these faults requires specialized algorithms. This paper tackles this complex issue through (1) fault-finding equations and the placement of current sensors, and (2) a new hybrid algorithm based on data from the fault-finding equations and current sensors. Numerous simulations using PSIM 2021 were conducted to verify this proposed solution. The hybrid algorithm presented here is original compared to previous studies. It is easy to understand, responds quickly, and can be implemented in systems with photovoltaic arrays of any size.
The fluoropolymers used in proton exchange membrane (PEM) water electrolysis are part of the broad OECD definition of per- and polyfluoroalkyl substances (PFAS), a family of substances subject to increasing regulation. Potential PFAS emissions during commercial operation have been investigated in PEM fuel cells, but have not been reported for PEM electrolyzers. Based on previous measurements of fluoride release rates in water, potential emissions of fluorinated substances are likely to be detectable during the onset of stack operation. This observation is extended to evaluating potential PFAS emissions by collecting and analyzing recirculated water samples from a multi-megawatt PEM electrolyser plant in the first ~2 weeks of operation. No PFAS substances were detected using U.S. EPA Method 1633, consistent with the lack of observed degradation based on cell voltage and fluoride measurements. Methodologies for selecting and handling water samples were established. Minimizing gas crossover and maintaining water quality during electrolyzer operation can mitigate potential chemical degradation via hydroxyl radical formation. Implementing dual uses of the reverse osmosis deionization system to provide water and wastewater treatment can increase closed-loop operation and minimize potential PFAS emissions from wastewater.
This study forecasts the power conversion efficiency (PCE) of organic solar cells using data from experiments with donors and non-fullerene acceptor materials. We built a dataset that includes both numerical and categorical features by using standard scaling and one-hot encoding. We developed and compared several machine learning (ML) models, including multilayer perceptron, random forest, XGBoost, multiple linear regression, and partial least squares. The modified XGBoost model performed best, achieving a root mean squared error (RMSE) of 0.564, a mean absolute error (MAE) of 0.446, and a coefficient of determination (R2) of 0.980 on the test set. We also assessed the model’s ability to generalize and its reliability by examining learning curve trends, calibration curve analysis, and residual distribution. Plots of feature correlation and permutation importance showed that ionization potential and electron affinity were key predictors. The results demonstrate that with proper tuning, gradient boosting methods can provide highly accurate and easy-to-understand predictions of organic solar cell efficiency. This work establishes a repeatable machine learning process to quickly screen and thoughtfully design high-efficiency photovoltaic materials.
This study investigates the thermal performance and freshwater productivity of a passive single-slope solar still under four distinct configurations, aimed at enhancing distillation efficiency using low-cost modifications. The experiments were conducted in Tabuk, Saudi Arabia (28°23′50″ N, 36°34′44″ E), a region characterized by high solar irradiance ranging from 847 to 943 W/m2. The baseline system, constructed with a stainless-steel basin and inclined transparent glass cover, served as the control, achieving a cumulative distillate yield of 3.237 kg/m2/day and a thermal efficiency of 36.27%. Subsequent modifications included the addition of external reflective mirrors (Experiment 2), aluminum foil foam insulation (Experiment 3), and internal enhancements with side glass panels and internal aluminum mirrors (Experiment 4). Results demonstrated that the external mirror modification improved the distillate yield by 16% to 3.757 kg/m2/day, with a corresponding efficiency of 41.66%. However, insulation under dusty conditions led to a reduced yield of 2.000 kg/m2 and an efficiency of 25.18%, highlighting the critical influence of solar transmittance. The most notable improvement was recorded in the fourth configuration, which combined internal reflective elements and transparent side panels, resulting in a maximum yield of 4.979 kg/m2/day and thermal efficiency of 56.45%. These findings confirm that optical and thermal design enhancements can significantly augment the performance of passive solar stills, especially under high-irradiance, clear-sky conditions. The proposed modifications are low-cost, scalable, and suitable for implementation in remote and arid regions facing freshwater scarcity. This study offers valuable insights into the systematic optimization of solar distillation systems to improve sustainable water production.