Indoor air treatment has become a significant concern in recent years. The aim of this study is to investigate the effectiveness of coupling adsorption and photocatalysis for the removal of toluene and formaldehyde, especially in the presence of optical fiber textile. First, we examine the adsorption properties of various commercial activated carbon (AC) filters, as well as different amounts of AC deposited on optical fiber textiles, and assess the impact of titanium dioxide (TiO2) on the adsorption performance. In the second phase, we compare the photocatalytic degradation of toluene and formaldehyde under different irradiance levels. Finally, we analyze the impact of three AC-TiO2 combinations: separate filters, TiO2 deposited on AC-impregnated fiber optic textiles, and TiO2 partially deposited on AC filters. The results led us to test a new photocatalytic and adsorbent material, including heating wires and optical fibers.