Preparation, Characterization and Performance Assessment of Metal Complexes of Curcuma longa Extract as Sensitizers for Dye-Sensitized Solar Cells

ABSTRACT: The dye extract of Curcuma longa (turmeric), which is very rich in curcumin, was chemically modified by complexation reaction with Zn²⁺, Cu²⁺, and Fe³⁺ ions to enhance its stability, electron transfer and photovoltaic performance. The dye and complexes were characterized by Ultraviolet-Visible (UV-Vis) absorption and Fourier Transform Infra-Red (FTIR) spectroscopy of potential chromophores and functional groups. The spectral data obtained indicated that the curcuminoid ligands were successfully coordinated with the metal centers, resulting in red-shifted absorption bands from beyond 460 nm and C=O vibrational frequency decreasing below 1650 cm⁻¹. Complexation reaction resulted in improved photochemical response and enhanced light-harvesting potential. When compared, the solar cells fabricated with titanium dioxide (TiO₂) photoanodes sensitized by the complexes afforded improvement in the magnitude of short-circuit current density as well as power conversion efficiency compared to the devices sensitized with the crude extract. Among the three complexes, the Zn-complex afforded the highest efficiency (1.20%), attributed to favourable electronic coupling and reduced recombination losses. Computational studies conducted through quantum chemical calculations based on the curcumin structure supported the experimental findings. The findings from this study demonstrate that metal ions-natural dye complexes have potential for application as low-cost, eco-friendly and sustainable sensitizers, thereby opening a novel horizon in green photovoltaic technologies.