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Article

24 December 2024

Hydrodynamic Performance of a Hybrid Floating Power Dock Combining Multi-Cantilever Type Buoys

This paper proposes a novel three-dimensional oscillating pendulum wave energy converter (WEC) that integrates an oscillating float dock station. The device captures wave energy by utilizing both the pitch and roll motions of its primary float and the pendular motion of a buoy. A time-domain analysis method is used to numerically evaluate the hydrodynamic behavior and energy conversion efficiency of the WEC. In ANSYS AQWA, a multi-cantilever WEC model is employed to address the fluid-solid coupling, calculating the device’s motion response and capturing the width ratio under various environmental conditions. Additionally, by modifying key geometric parameters including float radius, length, and cantilever angle, the study examines the rotation at the articulation point and the capture width ratio variation for different device configurations. Results indicate that the device achieves a maximum capture width ratio at a float radius of approximately 120 mm under T = 1.4 s, and a 130 mm for wave periods of 1.5 s and 1.6 s. The highest average capture width ratio is reached at a power take-off (PTO) damping coefficient of 400 N·s/m. The study further investigates the effect of cantilever angle and float length, aiding in the optimization of these geometric parameters.

Keywords: Wave energy; Hybrid system; Floating dock; Cantilevering type buoy; Potential flow theory; Capture width ratio

Article

27 November 2024

Photocatalytic CO2 Fixation into Formate under Visible Light by the Photo-Enzyme Hybrid of Gold Nanocapsules and Formate Dehydrogenase

The photo-enzyme hybrid system presents a promising approach for the selective conversion of CO2 into valuable chemicals. However, its high dependence on the expensive coenzyme nicotinamide adenine dinucleotide reduced form (NADH), coupled with the need for external electron mediators and highly active photocatalysts, limits its widespread application. Here, we developed a gold nanocapsuleformate dehydrogenase (FDH) hybrid system for in situ NADH regeneration to facilitate the light-driven conversion of CO2 to formate. The results demonstrated that gold nanocapsules (Au NCPs), in conjunction with triethanolamine (TEOA), protected 83.67% of NADH from photodegradation. Under light-driven conditions with TEOA as the electron donor and without external electron mediators, the Au NCPs catalyzed in situ NADH regeneration, achieving a regeneration yield of 22.65%. This process aided FDH in reducing CO2 to formate, resulting in a production rate of 67.40 µmol/L/h. This research provides valuable insights for developing photo-enzyme hybrid systems that efficiently convert CO2 without the need for external electron mediators.

Keywords: Photo-enzyme hybrid system; NADH regeneration; Gold nanocapsules; CO2 reduction; Formate
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